Search results for "Pi system"
showing 2 items of 2 documents
Branching fraction measurement ofB¯0→D(*)+π−andB−→D(*)0π−and isospin analysis ofB¯→D(*)πdecays
2007
Using 65 X 10(6) Y (4S) -> BB events collected with the BABAR detector at the PEP-II e(+) e(-) storage ring at the Stanford Linear Accelerator Center, we measure the color-favored branching fractions B(B-0 -> D+ pi(-)) = (2.55 +/- 0.05 +/- 0.16) X 10(-3), B(B-0 -> D*(+) pi(-)) = (2.79 +/- 0.08 +/- 0.17) X 10(-3), B(B- -> D-0 pi(-)) = (4.90 +/- 0.07 +/- 0.22) X 10(-3) and B(B- -> D*(0)pi(-)) = (5.52 +/- 0.17 +/- 0.42) X 10(-3), where the first error is statistical and the second is systematic. With these results and the current world average for the branching fraction for the color-suppressed decay B-0 -> D-(*()0)pi(0), the cosines of the strong phase difference delta between the I =1/2 and …
π conjugation across the tetrathiafulvalene core: Synthesis of extended tetrathiafulvalene derivatives and theoretical analysis of their unusual elec…
2000
A series of extended tetrathiafulvalene (TTF) derivatives bearing one or two 1,4-dithiafulven-6-yl substitutents has been prepared. The new compounds present remarkable electrochemical singularities compared with other TTF derivatives, which are strongly affected by the nature of the substitution on the lateral heterocycle(s). This unusual electrochemical behaviour follows a square-scheme sequence and is attributed to structural changes upon oxidation of the pi-donating molecules. Digital simulations of the electrochemical data have been used to reach the values of the kinetic and thermodynamic constants involved in the square scheme. Theoretical calculations establish an important contribu…